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CH3C(O)OCH2CH2CH3


kCl: 7.1 ± 2 x 10-11 cm3 molecule-1 s-1
T = 295 ± 2 K
Pressure Range : 700 Torr
Bath Gas : Nitrogen
Technique(s) : relative rate - Fourier transform spectroscopy
Source : Photolysis of Cl2
Commentary : Placed on an absolute basis using: k(Cl + Acetylene) = 5.07 × 10-11 cm3 molecule-1 s-1; k/kref = 1.46 ± 0.33 k(Cl + Ethene) = 9.29 × 10-11 cm3 molecule-1 s-1; k/kref = 0.732 ± 0.073 Quoted value is from the authors
R e f e r e n c e :
Xing J-H, Takahashi K., Hurley M. D. , Wallington T. J. ,
Kinetics of the reactions of chlorine atoms with a series of acetates
Chemical Physics Letters
2009, Vol. 474, pp 268-272
DOI : 10.1016/j.cplett.2009.04.083
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