CH3C(O)OCH2CH2CH3
kCl: 7.1 ± 2 x 10
-11 cm
3 molecule
-1 s
-1 T = 295 ± 2 K
Pressure Range : 700 Torr
Bath Gas : Nitrogen
Technique(s) : relative rate - Fourier transform spectroscopy
Source : Photolysis of Cl2
Commentary : Placed on an absolute basis using:
k(Cl + Acetylene) = 5.07 × 10
-11 cm
3 molecule
-1 s
-1; k/kref = 1.46 ± 0.33
k(Cl + Ethene) = 9.29 × 10
-11 cm
3 molecule
-1 s
-1; k/kref = 0.732 ± 0.073
Quoted value is from the authors
R e f e r e n c e :Xing J-H, Takahashi K., Hurley M. D. , Wallington T. J. , Kinetics of the reactions of chlorine atoms with a series of acetates
Chemical Physics Letters 2009,
Vol. 474, pp 268-272
DOI :
10.1016/j.cplett.2009.04.083