CHCl2CHO
kCl: 13 ± 2 x 10
-12 cm
3 molecule
-1 s
-1 T = 298 ± 2 K
Pressure Range : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - Fourier transform spectroscopy - gas chromatography
Source : Photolysis of Cl2
Commentary : Placed on an absolute basis using k(Cl+C6H5CH3)=5.59 × 10
-11
R e f e r e n c e :Scollard D. J. , Treacy J. , Sidebottom H. W., Balestra-Garcia C. , Laverdet G. , Le Bras G., MacLeod H. , Téton S. , Rate constants for the reactions of hydroxyl radicals and chlorine atoms with halogenated aldehydes
The Journal of Physical Chemistry 1993,
Vol. 97, pp 4683-4688