Chemical Kinetics Database ERADB

Formula : CH2=C(CH3)CH2CH2OH
Name : 3-Methyl-3-buten-1-ol
CAS : 763-32-6
Smiles : OCCC(=C)C
InChI=1S/C5H10O/c1-5(2)3-4-6/h6H,1,3-4H2,2H3
Function(s) : Alcohols
Family(ies) : Unsaturated Oxygenates
( More about this compound )

Page results : { 1 }

Constant 1 :
kOH: 9.4 ± 0.4 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Temperature Range: 263-369 K
Pressure : 100 Torr
Bath Gas : Helium
A = 5.5 ± 1.0 × 10^-12 cm³ molecule^-1 s^-1
E/R = -836 ± 54 K
Technique(s) : pulsed laser photolysis - laser induced fluorescence
Source : Photolysis of H2O2
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 2 :
kOH: 9.6 ± 1.8 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 750 Torr
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(propene) = 3.01 × 10^-11
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 3 :
kOH: 97 ± 8 × 10^-12 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 750 Torr
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(3-buten-2-ol) = 5.93 × 10^-11
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 4 :
kOH: 9.7 ± 1.8 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 750 Torr
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Average Value
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 5 :
kOH: 9.85 ± 1.08 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Technique(s) : relative rate - Fourier transform infrared
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using k(di-n-butyl ether) = 2.89 × 10^-11
R e f e r e n c e :
Imamura T. , Ida Y. , Obi K. , Nagatani I. , Nakagawa K. , Patroescu-Klotz I. , Hatakeyama S.
Rate coefficients for the gas-phase reactions of OH radicals with methylbutenols at 298 K
International Journal of Chemical Kinetics
2004, Vol. 36, pp 379-385
DOI : 10.1002/kin.20008

Constant 6 :
kOH: 9.52 ± 1.00 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Technique(s) : relative rate - Fourier transform infrared
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using k(propene) = 2.63 × 10^-11
R e f e r e n c e :
Imamura T. , Ida Y. , Obi K. , Nagatani I. , Nakagawa K. , Patroescu-Klotz I. , Hatakeyama S.
Rate coefficients for the gas-phase reactions of OH radicals with methylbutenols at 298 K
International Journal of Chemical Kinetics
2004, Vol. 36, pp 379-385
DOI : 10.1002/kin.20008

Constant 7 :
kOH: 97 ± 7 × 10^-12 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Technique(s) : relative rate - Fourier transform infrared
Source : Photolysis of CH3ONO
Comment : Average Value
R e f e r e n c e :
Imamura T. , Ida Y. , Obi K. , Nagatani I. , Nakagawa K. , Patroescu-Klotz I. , Hatakeyama S.
Rate coefficients for the gas-phase reactions of OH radicals with methylbutenols at 298 K
International Journal of Chemical Kinetics
2004, Vol. 36, pp 379-385
DOI : 10.1002/kin.20008

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