Chemical Kinetics Database ERADB

Representation of 2-Trifluoromethyl-butoxyfluoroethane

Formula : CF3OCF2CF2H
Name : 2-Trifluoromethyl-butoxyfluoroethane
CAS : ***
Smiles : ***
Function(s) : Ethers
Family(ies) : Halogenated Containing Oxygenates

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Constant 1 :
kCl: 27.0 ± 5.2 × 10^-17 cm³ molecule^-1 s^-1
T = 296 ± 2 K
Pressure : 700 Torr
Bath Gas : Air
Technique(s) : relative rate - Fourier transform infrared
Source : Photolysis of Cl2
Comment : Placed on an absolute basis using
k(Cl+CF3CF2H)=2.5 × 10^-16,
k(Cl+CHClF2)=1.7 × 10^-15 and
k(Cl+CF3CH3)=3.6 × 10^-17
R e f e r e n c e :
Sulbaek Andersen M. P., Nielsen O. J. , Wallington T. J. , Hurley M. D. , DeMore W. B.
Atmospheric chemistry of CF3OCF2CF2H and CF3OC(CF3)2H : reaction with Cl atoms and OH radicals, degradation mechanism, global warming potentials, and empirical relationship between k(OH) and k(Cl) for organic compounds
The Journal of Physical Chemistry A
2005, Vol. 109, pp 3926-3934
DOI : 10.1021/jp044635m

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