Chemical Kinetics Database ERADB

Representation of 2,2,3,3,3-Pentafluoro-1-propanol

Formula : CF3CF2CH2OH
Name : 2,2,3,3,3-Pentafluoro-1-propanol
CAS : 422-05-9
Smiles : OCC(F)(F)CF(F)(F)
InChI=1S/C3H5F5O/c4-3(5,2-9)1-8(6)7/h9H,1-2H2
Function(s) : Alcohols
Family(ies) : Halogenated Containing Oxygenates
( More about this compound )

Page results : { 1 }

Constant 1 :
kOH: 105 ± 5 × 10^-15 cm³ molecule^-1 s^-1
T = 298 K
Temperature Range: 250-430 K
Pressure : 04-juin Torr
Bath Gas : Helium
A = 14.0 ± 2.7 × 10^-13 cm³ molecule^-1 s^-1
E/R = 780 ± 60 K
Technique(s) : discharge flow - laser induced fluorescence
Source : H + NO2
R e f e r e n c e :
Tokuhashi K. , Nagai H. , Takahashi A. , Kaise M., Kondo S. , Sekiya A. , Takahashi M., Gotoh Y. , Suga A.
Measurement of the OH reaction rate constants with CF3CH2OH, CF3CF2CH2OH, and CF3CH(OH)CF3
The Journal of Physical Chemistry A
1999, Vol. 103, pp 2664-2672
DOI : 10.1021/jp983961x

Constant 2 :
kOH: 97.8 ± 3.7 × 10^-15 cm³ molecule^-1 s^-1
T = 298 K
Pressure : 15-70 Torr
Bath Gas : Argon - Helium
Technique(s) : pulsed laser photolysis - laser induced fluorescence
Source : O(1D) + H2O
R e f e r e n c e :
Tokuhashi K. , Nagai H. , Takahashi A. , Kaise M., Kondo S. , Sekiya A. , Takahashi M., Gotoh Y. , Suga A.
Measurement of the OH reaction rate constants with CF3CH2OH, CF3CF2CH2OH, and CF3CH(OH)CF3
The Journal of Physical Chemistry A
1999, Vol. 103, pp 2664-2672
DOI : 10.1021/jp983961x

Constant 3 :
kOH: 97.4 ± 3.5 × 10^-15 cm³ molecule^-1 s^-1
T = 298 K
Pressure : 15-70 Torr
Bath Gas : Argon - Helium
Technique(s) : flash photolysis - laser induced fluorescence
Source : O(1D) + H2O
R e f e r e n c e :
Tokuhashi K. , Nagai H. , Takahashi A. , Kaise M., Kondo S. , Sekiya A. , Takahashi M., Gotoh Y. , Suga A.
Measurement of the OH reaction rate constants with CF3CH2OH, CF3CF2CH2OH, and CF3CH(OH)CF3
The Journal of Physical Chemistry A
1999, Vol. 103, pp 2664-2672
DOI : 10.1021/jp983961x

Page results : { 1 }