Chemical Kinetics Database ERADB

Formula : CH3CH=CHCH2OH
Name : 2-Buten-1-ol
CAS : 6117-91-5
Smiles : OCC=CC
InChI=1S/C4H8O/c1-2-3-4-5/h2-3,5H,4H2,1H3
Function(s) : Alcohols
Family(ies) : Unsaturated Oxygenates
( More about this compound )

Page results : { 1 }

Constant 1 :
kOH: 8.1 ± 0.4 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Temperature Range: 263-370 K
Pressure : 100 Torr
Bath Gas : Helium
A = 6.9 ± 0.9 × 10^-12 cm³ molecule^-1 s^-1
E/R = -744 ± 40 K
Technique(s) : pulsed laser photolysis - laser induced fluorescence
Source : Photolysis of H2O2
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 2 :
kOH: 8.3 ± 1.5 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(propene) = 3.01 × 10^-11
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 3 :
kOH: 9.9 ± 1.0 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(3-buten-2-ol) = 5.93 × 10^-11
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 4 :
kOH: 1.1 ± 0.1 × 10^-10 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(2-propen-1-ol) = 5.5 × 10^-11
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 5 :
kOH: 1.0 ± 0.1 × 10^-10 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(propyl vinyl ether) = 1.0 × 10^-10
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Constant 6 :
kOH: 9.8 ± 1.5 × 10^-11 cm³ molecule^-1 s^-1
T = 298 ± 2 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Average Value
R e f e r e n c e :
Cometto P. M., Dalmasso P. R., Taccone R. A., Lane S. I. , Oussar F. , Dale V., Mellouki A. , Le Bras G.
Rate constants for thereactions of OH with a series of unsaturated alcohols between 263 and 371 K
The Journal of Physical Chemistry A
2008, Vol. 112, pp 4444–4450
DOI : 10.1021/jp7111186

Page results : { 1 }