Chemical Kinetics Database ERADB

Formula : CH3CH2CH2OCH2CH2OH
Name : 2-propoxyethanol
CAS : 2807-30-9
Smiles : CCCOCCO
InChI=1S/C5H12O2/c1-2-4-7-5-3-6/h6H,2-5H2,1H3
Family(ies) : Saturated Oxygenates
( More about this compound )

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Constant 1 :
kOH: 2.14 ± 0.60 × 10^-11 cm³ molecule^-1 s^-1
T = 297 ± 3 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using :
k(OH+2-pentanone)=(4.9±1.1) × 10^-12 and
k(OH+n-octane)=(8.7±2.2) × 10^-12
R e f e r e n c e :
Markgraf S. J. , Semples J. , Wells J. R.
The Hydroxyl Radical Reaction Rate Constant and atmospheric transformation Products of 2-propoxyethanol
International Journal of Chemical Kinetics
1999, Vol. 31, pp 315-322
http://www3.interscience.wiley.com/journal/55001624/abstract?CRETRY=1&SRETRY=0

Constant 2 :
kOH: 1.64 ± 0.07 × 10^-11 cm³ molecule^-1 s^-1
T = 297 ± 3 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using :
k(hexanol)=1.25 × 10^-11 and
k(heptanol)/k(hexanol) = 1.24
(both heptanol and hexanol were used as reference compounds)
R e f e r e n c e :
Stemmler K. , Kinnison D. J. , Kerr J. A.
Room temperature rate coefficients for the reactions of OH radicals with some monoethylene glycol monoalkyl ethers
The Journal of Physical Chemistry
1996, Vol. 100, pp 2114-2116
DOI : 10.1021/jp9520355

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