Chemical Kinetics Database ERADB

Formula : CH3CH2NO2
Name : Nitroethane
CAS : ***
Smiles : CC[N+](=O)[O-]
InChI=1S/C2H5NO2/c1-2-3(4)5/h2H2,1H3
Family(ies) : Nitrogen Containing Oxygenates
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Constant 1 :
kOH: 7.22 ± 0.82 × 10^-14 cm³ molecule^-1 s^-1
T = 298 ± 1 K
Temperature Range: 240-440 K
Pressure : 25-50 Torr
Bath Gas : Argon
A = 1.9 ± 0.5 × 10^-12 cm³ molecule^-1 s^-1
E/R = 960 ± 90 K
Technique(s) : flash photolysis - resonance fluorescence
Source : Photolysis of H2O
R e f e r e n c e :
Liu R. , Huie R. E. , Kurylo M. J. , Nielsen O. J.
The gas phase reactions of hydroxyl radicals with a series of nitroalkanes over the temperature range 240-440 K
Chemical Physics Letters
1990, Vol. 167, pp 519-523

Constant 2 :
kOH: 1.5 ± 0.5 × 10^-13 cm³ molecule^-1 s^-1
T = 295 ± 3 K
Pressure : 760 Torr
Bath Gas : Argon
Technique(s) : pulse radiolysis - absorption spectroscopy
Source : Radiolysis of Ar/H2O
R e f e r e n c e :
Nielsen O. J. , Sidebottom H. W., O'Farrell D. J., Donlon M., Treacy J.
Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2 and CH3CH2CH2CH2CH2NO2
Chemical Physics Letters
1989, Vol. 156, pp 312-318

Constant 3 :
kOH: 1.5 ± 0.1 × 10^-13 cm³ molecule^-1 s^-1
T = 295 ± 3 K
Pressure : 730-750 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using k(OH+2,2-dimethyl propane)=8.26e-13
R e f e r e n c e :
Nielsen O. J. , Sidebottom H. W., O'Farrell D. J., Donlon M., Treacy J.
Rate constants for the gas-phase reactions of OH radicals and Cl atoms with CH3CH2NO2, CH3CH2CH2NO2, CH3CH2CH2CH2NO2 and CH3CH2CH2CH2CH2NO2
Chemical Physics Letters
1989, Vol. 156, pp 312-318

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