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Representation of 2-Propen-1-ol
Formula : CH2=CHCH2OH
Name : 2-Propen-1-ol
CAS : 107-18-6
Smiles : OCC=C
InChI=1S/C3H6O/c1-2-3-4/h2,4H,1,3H2
Function(s) : Alcohols
Family(ies) : Unsaturated Oxygenates
( More about this compound )


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Constant 1 :
kOH: 5.0 ± 0.5 × 10-11 cm3 molecule-1 s-1
T = 298 ± 1 K
Temperature Range: 231-373 K
Pressure : 33-100 Torr
Bath Gas : Helium
A = 5.7 ± 0.2 × 10-12 cm3 molecule-1 s-1
E/R = -650 ± 52 K
Technique(s) : pulsed laser photolysis - laser induced fluorescence
Source : Photolysis of H2O2
R e f e r e n c e :
Le Person A., Solignac G. , Oussar F. , Daële V. , Mellouki A. , Winterhalter R., Moortgat G. K.
Gas phase reaction of allyl alcohol (2-propen-1-ol) with OH radicals and ozone
Physical Chemistry Chemical Physics
2009, Vol. 11, pp 7619-7628
DOI : 10.1039/b905776e

Constant 2 :
kOH: 4.49 ± 0.02 × 10-11 cm3 molecule-1 s-1
T = 298 ± 3 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(OH+butyl vinyl ether)=1.0×10-10
k/kref=(0.449±0.002)
R e f e r e n c e :
Le Person A., Solignac G. , Oussar F. , Daële V. , Mellouki A. , Winterhalter R., Moortgat G. K.
Gas phase reaction of allyl alcohol (2-propen-1-ol) with OH radicals and ozone
Physical Chemistry Chemical Physics
2009, Vol. 11, pp 7619-7628
DOI : 10.1039/b905776e

Constant 3 :
kOH: 5.1 ± 0.2 × 10-11 cm3 molecule-1 s-1
T = 298 ± 3 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(OH+butyl vinyl ether)=1.0×10-10
k/kref=(0.506±0.020)
R e f e r e n c e :
Le Person A., Solignac G. , Oussar F. , Daële V. , Mellouki A. , Winterhalter R., Moortgat G. K.
Gas phase reaction of allyl alcohol (2-propen-1-ol) with OH radicals and ozone
Physical Chemistry Chemical Physics
2009, Vol. 11, pp 7619-7628
DOI : 10.1039/b905776e

Constant 4 :
kOH: 5.3 ± 0.8 × 10-11 cm3 molecule-1 s-1
T = 298 ± 3 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(OH+isopropenyl acetate)=6.96×10-11
k/kref=(0.757±0.007)
R e f e r e n c e :
Le Person A., Solignac G. , Oussar F. , Daële V. , Mellouki A. , Winterhalter R., Moortgat G. K.
Gas phase reaction of allyl alcohol (2-propen-1-ol) with OH radicals and ozone
Physical Chemistry Chemical Physics
2009, Vol. 11, pp 7619-7628
DOI : 10.1039/b905776e

Constant 5 :
kOH: 5.4 ± 0.9 × 10-11 cm3 molecule-1 s-1
T = 298 ± 3 K
Pressure : 760 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of H2O2
Comment : Placed on an absolute basis using k(OH+isopropenyl acetate)=6.96×10-11
k/kref=(0.780±0.020)
R e f e r e n c e :
Le Person A., Solignac G. , Oussar F. , Daële V. , Mellouki A. , Winterhalter R., Moortgat G. K.
Gas phase reaction of allyl alcohol (2-propen-1-ol) with OH radicals and ozone
Physical Chemistry Chemical Physics
2009, Vol. 11, pp 7619-7628
DOI : 10.1039/b905776e

Constant 6 :
kOH: 6.74 ± 1.35 × 10-11 cm3 molecule-1 s-1
T = 298 ± 1 K
Temperature Range: 282-315 K
Pressure : 760 Torr
Bath Gas : Air
A = 1.68 ± 0.89 × 10-12 cm3 molecule-1 s-1
E/R = -1100 K
Technique(s) : relative rate - gas chromatography
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using k(OH + a-pinene) = 1.21 × 10-11 exp(436/T) and k(OH + 1,3,5-trimethylbenzene) = 6.3 × 10-12 exp(670/T)
T=282 K : relative rate ratio = 1.21±0.08 (a-pinene)
T=282 K : relative rate ratio = 1.43±0.06 (TMB)
T=293 K : relative rate ratio = 1.44±0.05 (a-pinene)
T=300 K : relative rate ratio = 1.04±0.12 (TMB)
T=300 K : relative rate ratio = 1.31±0.18 (a-pinene)
T=307 K : relative rate ratio = 1.09±0.08 (TMB)
T=307 K : relative rate ratio = 1.30±0.07 (a-pinene)
T=315 K : relative rate ratio = 1.07±0.05 (TMB)
T=315 K : relative rate ratio = 1.16±0.05 (a-pinene)
R e f e r e n c e :
Parker J. K., Espada-Jalad C.
Kinetics of the gas phase reactions of OH and NO3 radicals and O3 with allyl alcohol and allyl isocyanate
The Journal of Physical Chemistry A
2009, Vol. 113, Issue 36, pp 9814–9824
DOI : 10.1021/jp9055939

Constant 7 :
kOH: 4.60 ± 0.19 × 10-11 cm3 molecule-1 s-1
T = 298 ± 2 K
Pressure : 100 Torr
Bath Gas : Helium
Technique(s) : pulsed laser photolysis - laser induced fluorescence
Source : Photolysis of 2,4-pentanedione
R e f e r e n c e :
Holloway A. L. , Treacy J. , Sidebottom H. W., Mellouki A. , Daële V. , Le Bras G., Barnes I.
Rate coefficients for the reactions of OH radicals with the keto/enol tautomers of 2,4-pentanedione and 3-methyl-2,4-pentanedione, allyl alcohol and methyl vinyl ketone using the enols and methyl nitrite as photolytic sources of OH
Journal of Photobiology and Biochemistry A: Chemistry
2005, Vol. 176, pp 183-190
DOI : 10.1016/j.jphotochem.2005.08.031

Constant 8 :
kOH: 4.5 ± 0.6 × 10-11 cm3 molecule-1 s-1
T = 298 ± 2 K
Pressure : 700 Torr
Bath Gas : Air
Technique(s) : relative rate - Fourier transform infrared
Source : Photolysis of C2H5ONO
Comment : Placed on an absolute basis using k(propene) = 2.63 × 10-11
R e f e r e n c e :
Orlando J. J. , Tyndall G. S. , Ceazan N.
Rate coefficients and product yields from reaction of OH with 1-penten-3-ol, (Z)-2-penten-1-ol, and allyl alcohol (2-propen-1-ol)
The Journal of Physical Chemistry A
2001, Vol. 105, pp 3564-3569
DOI : 10.1021/jp0041712

Constant 9 :
kOH: 5.46 ± 0.35 × 10-11 cm3 molecule-1 s-1
T = 296 ± 2 K
Pressure : 740 Torr
Bath Gas : Air
Technique(s) : relative rate - gas chromatography
Source : Photolysis of CH3ONO
Comment : Placed on an absolute basis using k(1,3,5-trimethylbenzene) = 5.7 × 10-11
R e f e r e n c e :
Papagni C. , Arey J. , Atkinson R.
Rate constants for the gas-phase reactions of OH radicals with a series of unsaturated alcohols
International Journal of Chemical Kinetics
2001, Vol. 33, pp 142-147
DOI : 10.1002/1097-4601(200102)33:2<142::

Constant 10 :
kOH: 37 ± 5 × 10-12 cm3 molecule-1 s-1
T = 298 ± 2 K
Pressure : 10.0-20.0 Torr
Bath Gas : Argon
Technique(s) : pulsed laser photolysis
Source : Photolysis of Allyl Alcohol
R e f e r e n c e :
Upadhyaya H. P., Kumar A., Naik P. D., Sapre A. V., Mittal J.P.
Kinetics of OH radical reaction with allyl alcohol (H2C=CHCH2OH) and propargyl alcohol (HCCCH2OH) studies by LIF
Chemical Physics Letters
2001, Vol. 349, pp 279-285
DOI : 10.1016/S0009-2614(01)01218-0

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